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A molecular beam is produced by allowing a gas at higher pressure to expand through a small orifice into a chamber at lower pressure to form a Particle beam (, , or ) moving at approximately equal velocities, with very few between the particles. Molecular beams are useful for fabricating in molecular beam epitaxy and artificial structures such as , , and . Molecular beams have also been applied as crossed molecular beams. The molecules in the molecular beam can be manipulated by and . Molecules can be decelerated in a Stark decelerator or in a Zeeman slower.
In 1921, Hartmut Kallmann and Fritz Reiche wrote" about the deflection of beams of polar molecules in an inhomogeneous electric field, with an ultimate aim of measuring their dipole moments. Seeing the page proofs for the Kallman and Reiche work prompted Otto Stern at the University of Hamburg and University of Frankfurt am Main to rush publication of his work with Walther Gerlach on what later became known as the Stern–Gerlach experiment. (Stern's paper references the preprint, but the Kallman and Reiche work would go largely unnoticed.)
When the 1922 Stern-Gerlach paper appeared is caused a sensation: they claimed to have experimentally demonstrated "space quantization": clear evidence of quantum effects at a time when classical models were still considered viable. The initial quantum explanation of the measurement -- as an observation of orbital angular momentum -- was not correct. Five years of intense work on quantum theory was needed before it was realized that the experiment was in fact the first demonstration quantum electron spin Stern's group would go on to create pioneering experiments with atomic beams, and later with molecular beams. The advances of Stern and collaborators led to decisive discoveries including: the discovery of space quantization; de Broglie Matter wave; anomalous magnetic moments of the proton and neutron; Atomic recoil of emission of a photon; and the limitation of scattering cross-sections for molecular collisions imposed by the uncertainty principle
The first to report on the relationship between dipole moments and deflection in a molecular beam (using binary salts such as KCl) was Erwin Wrede in 1927."
In 1939 Isidor Rabi invented a molecular beam magnetic resonance method in which two magnets placed one after the other create an inhomogeneous magnetic field. The method was used to measure the magnetic moment of several lithium isotopes with molecular beams of lithium chloride, lithium fluoride and dilithium. The Rabi molecular-beam method - The Feynman Lectures on Physics This method is a predecessor of NMR. The invention of the maser in 1957 by James P. Gordon, Herbert J. Zeiger and Charles H. Townes was made possible by a molecular beam of ammonia and a special electrostatic quadrupole focuser.
The study of molecular beam led to the development of molecular-beam epitaxy in the 1960s.
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